Which process is used to obtain chromium by reducing chromium(III) oxide with aluminium?
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Chromium can be obtained from chromium(III) oxide by the aluminothermic, or thermite, process. Finely divided aluminium reduces Cr₂O₃ in a highly exothermic reaction: Cr₂O₃ + 2Al → Al₂O₃ + 2Cr + heat. Aluminium has a stronger affinity for oxygen, so it removes oxygen from chromium oxide and releases molten chromium. The process is used for reducing oxides of metals whose extraction by carbon may be unsuitable. Froth flotation concentrates sulphide ores, zone refining purifies already-produced metals or semiconductors, and electrolysis is used for selected extraction or refining operations. The reaction and aluminium’s role are the main exam points. Concept depth: The aluminothermic process uses aluminium powder as a powerful reducing agent for certain metal oxides.